ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    东昆仑洪水河锰矿床成矿过程:来自地层学、矿物学和地球化学的证据

    Ore-Forming Processes of the Hongshuihe Manganese Deposit, East Kunlun Orogen: Constraints from Stratigraphy, Mineralogy, and Whole-Rock Geochemistry

    • 摘要: 洪水河锰矿床位于东昆仑造山带北缘与柴达木盆地南缘过渡部位,矿体赋存于狼牙山组浅变质碎屑岩–碳酸盐岩组合中,其沉积环境、锰质来源及成矿过程尚缺乏系统认识。笔者综合运用实测地层剖面、矿物学及全岩地球化学资料,对含锰岩系的沉积演化、成矿物质来源、水体氧化还原条件及矿床形成过程进行了系统研究。结果表明,矿石主要由菱锰矿、钙菱锰矿、锰方解石、蔷薇辉石及锰氧化物组成,记录了沉积–成岩阶段碳酸锰形成、构造–热液阶段硅酸锰重结晶以及近地表氧化的成矿–改造演化过程。洪水河含锰岩系形成于浅海台地–局限盆地沉积体系,主要由碳酸盐岩和碎屑岩–碳酸盐岩混积组合构成,锰矿层集中发育于碎屑沉积向碳酸盐沉积转换的关键层位,沉积相带迁移及沉积期水体环境转换对矿层定位具有重要控制作用。V/Cr、Ni/Co、V/(V+Ni)、Ce异常及Mo-U富集特征共同表明,锰沉积期水体总体处于氧化–次氧化状态,而非持续强还原或稳定硫化环境。MnO与Al2O3、TiO2相关性较弱,结合(Fe+Mn)/Ti和Al/(Al+Fe+Mn)等图解,指示火山–热液活动为盆地提供了重要的Mn、Si等成矿组分,伴有一定程度的陆源碎屑输入和海水再分配。综合研究,洪水河锰矿床的形成经历了沉积–早成岩成矿、后期构造–热液和表生氧化阶段连续演化过程。矿床应属受火山–热液活动影响的沉积变质型锰矿床。

       

      Abstract: The Hongshuihe manganese deposit is located in the transitional zone between the northern margin of the East Kunlun Orogen and the southern margin of the Qaidam Basin. The orebodies are hosted in a weakly metamorphosed siliciclastic-carbonate succession of the Langyashan Formation, yet the depositional environment, sources of manganese, and ore-forming processes remain poorly constrained. This study integrates measured stratigraphic sections, mineralogical observations, and whole-rock geochemical data to investigate the depositional evolution of the Mn-bearing succession, the sources of ore-forming materials, the redox conditions of the water column, and the processes of Mn mineralization. The ores consist mainly of rhodochrosite, calcian rhodochrosite, manganoan calcite, rhodonite, and Mn oxides, recording three principal stages: formation of Mn carbonates during sedimentation and diagenesis, tectono-hydrothermal recrystallization of Mn silicates, and near-surface oxidation. The Mn-bearing succession was deposited in a shallow-marine platform-restricted basin system and is composed mainly of carbonate rocks and mixed siliciclastic–carbonate assemblages. Mn mineralization is concentrated at key stratigraphic intervals marking the transition from siliciclastic-dominated to carbonate-dominated sedimentation, indicating that facies migration and reorganization of the depositional system exerted an important control on the localization of the Mn-rich horizons. V/Cr, Ni/Co, V/(V+Ni), Ce anomalies, and Mo-U enrichment patterns collectively indicate that the water column during Mn deposition was generally oxic to suboxic rather than persistently strongly reducing or euxinic. The weak correlations of MnO with Al2O3 and TiO2, together with the (Fe+Mn)/Ti and Al/(Al+Fe+Mn) discrimination diagrams, suggest a significant volcanic-hydrothermal contribution of Mn- and Si-bearing components to the basin, with additional terrigenous detrital input and subsequent redistribution within seawater. Overall, the Hongshuihe manganese deposit records a multistage evolutionary history comprising sedimentary-early diagenetic mineralization, subsequent tectono-hydrothermal modification, and supergene oxidation. The deposit is therefore interpreted as a sedimentary manganese deposit influenced by volcanic–hydrothermal input and subsequently modified by tectono-hydrothermal and supergene processes..

       

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